Record #204746 - GSI Repository

HALOBORYLATION

Electrophilic-induced asymmetric boronate rearrangements via CAPT catalysis. A novel approach towards the formal trifunctionalization of alkenes.

Coordinator	THE CHANCELLOR MASTERS AND SCHOLARSOF THE UNIVERSITY OF CAMBRIDGE
Grant period	2017-11-01 - 2019-10-31
Funding body	European Union
Call number	H2020-MSCA-IF-2016
Grant number	744604
Identifier	G:(EU-Grant)744604

Note: This proposal describes an unprecedented, enantioselective haloborylation reaction through the innovative application of chiral anion phase-transfer (CAPT) catalysis to electrophilic-induced boronate rearrangements. Beyond the development of an orthogonal approach towards the formal trifunctionalization of alkenes, the proposed methodology provides easy access to biologically and synthetically important products, and is anticipated to have great impact in the area of diversity oriented synthesis.

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Record created 2017-06-14, last modified 2023-02-14

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